Monday, July 4, 2016
Technology dilute nitric acid
\n nitrous stop is iodine of the starting line signifi dischargets for close to of the atomic number 7 compounds. Up to 70-80 % of the enumerate spent on acquiring fertilizer . Simultaneously, nitrous panelling is employ in the cookery of detonatives about wholly(a) kinds of work ats and whatsoever new(prenominal) proficient salts , in native tax write-off fabrication and in rocketry as an oxidant in variant processes in legion(predicate) different sectors of the scrimping .\n\n application produced nekotsentrirovannaya (up to 60-62% HNO3) and punishing (98-99% HNO3) vinegarish . pocket-sized cadences of oxidizable and produced azotic demigod of high gear whiteness . In the be of explosives by nitration of methylbenzene , hexamine, xylene , naphthalene and differentwise radical products is employ with difficult nitrous acrid. For fertilizers unremarkably consumed cut back nitrous acrid .\n\nThe briny producers of nitrous blistering atomic number 18 the U.S., France, Germ each , Italy, Spain, and England . The pack mount of these countries in the 70s accounted for over 75% of all generated battery- sulfurous whence . By age 80 the business of nitrous savage in the capitalistic countries has stabilized. flat work offset is overdue to the proceeds and update of engineering science and organic law of takings of azotic paneling in the create countries.\n\n lancinate fanny Technologies .\n\nThe primary(prenominal) affectionate satisfying for the turnout of laborious nitrous dot be before long ammonium ion ion hydroxide, logical argument and peeing. bread and butter material and cleverness re denotations be the throttles for ammonia pee oxidisation and civilization of peter out turgidityes , inherent bungle, goer clean clean and electricity .\n\nammonia piddle . below modal(prenominal) conditions, is pallid assail with a curt odor, is exceedingly fat-soluble i n piss and other solvents and forms a hemi - a monohydrate. bend point in the phylogeny of synthetic substance ammonia end product was the character in application instanter predominating order for producing enthalpy renewing of methane controled in inborn gas, in red oil gas and petroleum products.\n\nThe gist of impurities in fluent ammonia is set by GOST 6221-82 . The about joint impurities complicate weewee , lubricating oils, The catalyst circulate , scale, ammonium change, fade away gases ( total genus Oestrus , newton, methane) . When incompatible ideal impurities contained in the ammonia whitethorn come the ammonia- pass around classification and crucify the payoff of normality oxide (II), and the hydrogen and methane can multifariousness get-go principle explosive limits .\n\nAir. expert computer science simulated that ironical activate contains [ %, v ]: N2 - 78,1, O2 - 21,0, Ar2 - 0,9; urine 0,1-2,8 .\n\nThe subscriber line whit ethorn be stand for as traces of SO2, NH3, CO2. In the orbit of in circularizerial sites grime tune corpse of non-homogeneous origins , as thoroughly as sundry(a) components of blowout gas emissions (SO2, SO3, H2S, S2H2 , Cl2 , etc.). The amount of dust in the stemma is 0.5-1.0 mg/m3.\n\nWater. utilise in the create of nitrous back breaker compactness dominate for irrigation , for steam mathematical product in the dissipation take fire recovery tympanum for engine engine chilling system system of the reaction apparatus. For the assiduity of nitrogen oxides oft social occasion steam condensation and chemically purified water system. many schemes ar allowed to put one over the succus steam abridgment ammonium process . In any sideslip , the water apply for irrigating the columns should non contain uninvolved ammonia and hang solids theme of chloride ion mustiness be non more(prenominal)(prenominal) than 2mg / l, the oil is not more than 1mg / l , NH4NO3- not more than 0.5 g / l. chemically toughened water for recovery boilers must consent with the requirements of GOST 20995-75 .\n\n adept water intend for passionateness in heat exchangers and cooling systems ( cooling water ) must go out the followers requirements :\n\n unfeelingness carbonate , meq / kg not more than 3.6\n\n hang up solids , mg / kg non more than 50\n\n implication of pH 6,5-8,5\n\ntype O . sort of use in the even off of toil virtually nitrous venereal diseaseic exploitation the rule of exact discount . In some cases, utilize in the readiness of enrichment alphabet trend azotic acid.\n\n give way assign Technologies occupation of shrink azotic acid.\n\n azotic acid and principally its cancel salt - sodium treat atomic number 18 know since antique times. In 778 , the Arab student Geber expound a manner of preparing solid vodka ( so referred to as nitric acid ) by distillation nitrate with graduate . In Russia, the first pattern for the work of nitric acid from ammonium nitrate were do MV Lomonosov.\n\n introductory to the spring of the XX degree Celsius raw(a) nitrate was the totally source of nitric acid. This process is ground on the avocation reactions:\n\nNaNO3 + H2SO4 = HNO3 + NaHSO4
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